Dr.
Dr.
RESEARCH
The
advanced oxidation technologies are mainly based in the generation of the hidroxil radical, which has a high oxidation power (only
fluorine is more oxidant than the hydroxyl radical). The potential applications
of the AOT are in the water treatment (drinking water) and in the wastewater
treatment.
Among the different advanced oxidation processes the group does research in
those which use:
and the combination of the AOT with the conventional
biological treatment.
Actually, we are studying
the integration of the AOP with the conventional biologic treatment in order to
make more economic the pollutants degradation. In the experimentation it is
necessary to follow the concentration of pollutants, COD, TOC and BOD. All
these analysis are performed to know if the effluent has decreased its toxicity
and increased its biodegradability in order to be treated by a biological way,
which is more economic than the AOP treatment. This research follows previous
work performed by Dr.
To obtain the experimental
data, we have the appropriate analysis instrumentation (HPLC, GC, spectrophotometry, TOC, COD, BOD).
Additionally there is the Serveis científico-tècnics
de la Universitat de Barcelona for more sophisticate analysis (BET, TEM,
SEM....).
The research performed involves some common pollutants as phenol, chlorophenols, 2,4-D, 2,4-DOH, atrazine, malathion, parathion,
phenols, anilines, emergent pollutants as NSAID, wastewater from pharmaceutical
and pulp and paper industry.
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Research Group (1995):
Dr.
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Research Group (2001):
Dr.
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Research Group (2007)
PhD advisers:
PhD candidates:
Jordi Bacardit, Alessandra Diniz Coelho,
Lêda Cristina Da Silva,
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http://www.tesisenxarxa.net/TDX-0913107-110817/index.html
Coupled photochemical-biological system to treat biorecalcitrant wastewaters
Jordi Bacardit Peñarroya
6 July 2007 PhD Thesis University of Barcelona (SPAIN) http://www.tesisenxarxa.net/TDX-0719107-132020/index.html
"Treatment of
bleaching waters in the paper industry"
C. Prat,
Water Research, 22, 663 668 (1987)
"Ozonization
of Bleaching Waters of the Paper Industry"
Wat.Res.,
23, 51-55 (1989)
C. Prat,
"Ozone and ozone/UV
treatments of bleaching waters of the paper industry in a tubular multilamp photoreactor"
C. Prat,
Industrial and Engineering Chemistry Research, 29, 349-355 (1990)
"Tubular multi-u.v. lamp reactor for water and wastewater treatment: I.
Radiation field"
O.M. Alfano,
Industrial Engineering Chemistry, 29, (7), 1270-1278 (1990)
"Tubular multi-uv lamp reactor for water and wastewater treatment: II
Reactor design and experimental verification"
Industrial Engineering Chemistry, 29, (7), 1278-1283 (1990)
O.M. Alfano,
"Effect of the
reflector shape on the performance of multi-lamp photoreactors
applied to pollution abatement"
Industrial Engineering Chemistry, 29, (7), 1283-1289 (1990)
O.M. Alfano,
"Photochemical
degradation of parathion in aqueous solutions"
Water Research, 26 (7), 911-915 (1992)
E. Gal, P. Aires, E. Chamarro and
"Photochemical
degradation of malathion in aqueous solutions"
Journal of Photochemistry 68, 121-129 (1992)
P. Aires, E. Gal, E. Chamarro and
"Photodecomposition of
2,4-dichlorophenoxyacetic acid: influence of pH"
Journal of Chemical Technology and Biotechnology, 57, 273-279 (1993)
"A jacketted annular membrane photocatalytic
reactor for wasterwater treatment. Degradation of formic and atrazine"
G. Chester,
Journal of Photochemistry, 71, 291-297 (1993)
"Photochemical
elimination of pesticides in wastewater"
Trends in Chemical Engineering, 1, 15-24 (1993)
E. Chamarro and
"Degradation of
4-chlorophenol by photolytic oxidation"
Water Research, 28 (6), 1323-1328 (1994)
"Degradation of 2,4-D by ozone and light"
Ozone Science and Engineering, 16 (3), 235-245 (1994)
J. Prado, J. Arantegui, E. Chamarro and
"Kinetics of the UV degradation of atrazine in
aqueous solution in the presence of hydrogen peroxide"
J. Arantegui, J. Prado, E. Chamarro and
Journal of Photochemistry 88
(1995) 65-74
"Métodos de eliminación
de pesticidas persistentes"
E. Chamarro and
Química e Industria, 42 (6),
(1995) 359-365
“Tratamiento de aguas y
aguas residuales mediante la utilización de Procesos de Oxidación
Avanzada”
E. Chamarro, A. Marco, J.
Prado and
Química & Industria
(CHILE), 1, 28-32 (1996)
ISSN 0716 -7083
“Oxidation of aromatic
compounds with uv radiation/ozone/hydrogen peroxide"
A.
Mokrini, D. Oussi and
Water Science and Technology, 35 (4), 95-102 (1997)
"How and why to combine chemical and biological processes for
wastewater treatment"
A. Marco,
Water Science and Technology, 35 (4), 321-327 (1997)
“Removal of Aromatic
Compounds using UV/H2O2”.
D.
Oussi, A: Mokrini and
Trends in Photochemistry and Photobiology, 1, 77-83 (1997)
"Process integration development: reactor kinetic models for
sequential chemical + biological oxidation for water treatment"
ICOA,s Fourth International Symposium
Edited by Eckenfelder, Vol 4, 7-21 (1994)
“Economic aspects of
integrated (chemical+biological) processes for wastewater treatment.”
Journal of Advanced Oxidation Technologies, 2 (1), 197-202 (1997)
“Comparison of Different
Advanced Oxidation Processes Involving Ozone for the Treatment of Atrazine in
Aqueous Solution”
J. Prado, and
EPRI, 4, 43 – 53 (1997)
“Photodecomposition of the
sex pheromones of cydia pomonella and lobesia botrana in aqueous
solutions”
R. Panades, A. Ibarz,
CHEMOSPHERE, 36 (3), 427-434
(1998)
“Descomposición fotoquímica de indol en
solucion acuosa"
Ibarz, A., Tejero, J.M.,
Panades, R. and Esplugas, S.
Tecnología del agua 173 ,
47-60 (1998)
“Photodegradation of Benzoic Acid In Aqueous
Solutions"
Driss Oussi, Asmae Mokrini,
Environmental Technology, 19, 955-960 (1998)
“Photoxidation of Phenol in
Aqueous Solutions"
A. Mokrini, D. Oussi,
Internet Photochemistry and Photobiology
17th IUPAC Symposium on Photochemistry
Virtual Session Papers
http://www.photobiology.com/IUPAC98/page2.htm
http://www.photobiology.com/IUPAC98/esplugas/phenol.html
July 1998
“Comparison of Different Advanced Oxidation Processes Involving
Ozone to Eliminate Atrazine”
Ozone Science and Engineering, 21, 39-52 (1999)
“Degradation of phenol in aqueous solutions using fe+3 and uv
radiation”
Récents
Progrès en Genie des Procédès, 13 (70), 279-286 (1999)
ISBN 2-910239-44-6
“Oxidación avanzada en
el tratamiento de aguas residuales”
Javier Baraza,
Tecnología del Agua, 197,
82-92 (2000)
“Descomposición del
ácido fórmico mediante O3/H2O2.”
Javier Baraza,
Afinidad, 57, 88-92 (2000)
“Influence of H2O2
and Fe(III) in the photodegradation of nitrobenzene”
Journal of Photochemistry and Photobiology A: Chemistry, 133 (1-2),
123-127 (2000)
“Oxidation of nitrobenzene by
O3/uv: influence of H2O2 and Fe
(III)” “Experiences in pilot
plant”.
Rodríguez, M., Contreras, S., Chamarro, E., Esplugas, S., Casado, J.
Oxidation Technologies for Water and Wastewater Treatment. (46), 14-15 (2000)
A.Vogephol
(ed.) (2000) Clausthal-Zellerfeld (GERMANY)
ISBN 3-89720-392-9.
“Kinetic parameters for the
degradation of phenol in the Fe(II)/H2O2 system”
Timokhin, V., Rodríguez, M., Contreras, S. , Chamarro, E., and Esplugas, S.
Oxidation Technologies for Water and Wastewater Treatment. (46), 89-90 (2000)
A.Vogephol
(ed.) (2000) Clausthal-Zellerfeld (GERMANY)
ISBN 3-89720-392-9.
“Iron (iii) photoxidation of aromatic compounds in aqueous
solutions”
Rodríguez, M., Kirchner, A., Contreras, S., Chamarro, E., Esplugas, S.
Oxidation Technologies for Water and Wastewater Treatment. (46), 185-186 (2000)
A.Vogephol
(ed.) (2000) Clausthal-Zellerfeld (GERMANY)
ISBN 3-89720-392-9.
“Photodecomposition of carbendazim in aqueous solutions”
Panades P, Ibarz A, Esplugas S
Water Research 34: (11) 2951-2954 AUG 2000
“Use of fenton reagent to improve organic chemical
biodegradability”
Chamarro, E., Marco, A., Esplugas, S.
Water Research 35 (4), 1047-1051 (2001)
“Simple kinetic models for the evaluation of BOD and COD in chemical
oxidation treatments”
Chemie Ingenieur Technik 73 (6), 606 (2001)
ISBN 0009-286 X
“Oxidation of nitrobenzene by
O3/UV : influence of H2O2
and Fe (III). Experiences in pilot plant”
Contreras, S, Rodríguez, M., Chamarro, E., Esplugas, S., Casado, J.
Water Science and Technology, 44 (5), 39-46 (2001)
“UV- and UV/Fe(III) enhanced
ozonation of nitrobenzene in aqueous solution”
Contreras, S, Rodríguez, M., Chamarro, E., Esplugas, S.
Journal of Photochemistry and Photobiology A: Chemistry, 142, 79-83 (2001)
“Comparison of different advanced oxidation processes for phenol
degradation”
Water Research, 36 (4), 1034-1042 (2002)
“Iron(III) photooxidation of aromatic compounds in aqueous
solutions”
Rodríguez, M., Abderrazik, N., Contreras, S., Chamarro, E., Gimenez, J ., Esplugas, S.
Applied
Catalysis B, Environmental, Vol. 37 (2) (2002) pp. 131-137
" Combined advanced oxidation with biological treatment"
N. Ben Abderrazik, F. Al Momani, C.
Sans,
Afinidad, 59,
141-146 (2002)
" Photo-Fenton treatment of a biuorecalcitrant wastewater generated in textile activities. Biodegradability of the photo-reacted solution."
J.Photochem and Photobiol A: Chemistry 151,
129-135 (2002)
"The
influence of different irradiation sources on the treatment of
nitrobenzene"
Catalysis
Today 76/2-4 pp. 291-300 (2002)
" Effects of radiation absorption and catalyst concentration on the photoatalytic
degradation of polutants"
David Curcó, Jaime Giménez, Abdel Addardak,
Catalysis
Today 76/2-4 pp. 177-188
(2002)
"Biodegradability improvement by photoFenton reaction"
N. Ben Abderrazik, F. Al
Momani,
Afinidad 59, 391-398 (2002)
" Rate Equation for the Degradation of Nitrobenzene by
"Fenton-Like Reagent"
Miguel L.
Advances in Environmental Research 7 (2003) 583-595
“Sequential Ozonation and biologicall oxidation of wastewater: A
model including biomass inhibition by residual oxidant”
Ozone Science and Enginering
25, 95-105 (2003)
“Mineralization of phenol in aqueous solution by ozonation using
iron or copper salts and light”
Applied Catalysis B: Environmental
2003 , 43:2:139-149
“Contribution
of the ozonation pre-treatment to the biodegradation
of aqueous solutions of 2,4-dichlorophenol”
Water Research 37
(13), 3164 - 3171 (2003)
“Degradation
of chlorophenols by means of advanced oxidation
processes: a general review”
Marc Pera-Titus, Verónica García-Molina, Miguel A. Baños,
Aplied
Catalysis B: Environmental 47, (4), 219-256
(2004)
“A comparative study of the advanced oxidation of 2,4-dichlorophenol
“
Journal of Hazardous Materials
Volume 107, Issue 3 ,
“Combining photo-Fenton process with biological sequencing batch
reactor for 2,4-dichlorophenol degradation”
Al Momani, F.; Gonzalez, O.;
Sans, C.; Esplugas, S..
Water Science and Technology
(2004), 49(4, Oxidation
Technologies for Water and Wastewater Treatment III), 293-298.
“Engineering Aspects of the Integration of Chemical and Biological
Oxidation: Simple Mechanistic Models for the Oxidation Treatment”
Journal of Environmental Engineering 130, 967-974 (2004)
“Wet peroxide oxidation of chlorophenols”.
Verónica García-Molina, Marta López-Arias,
Magdalena Florczyk,
“Photocatalytic degradation of 2,4-dichlorophenol
by TiO2/UV: kinetics, actinometries and models”
B. Bayarri, J. Giménez, D. Curcó and
Catalysis Today, 101,
227-236 (2005)
“Biodegradability improvement of aqueous
2,4-dichlorophenol and nitrobenzene solutions by means of single
ozonation”
Ozone Science and Engineering 27 (5) , 381-387 (2005)
“Optimizing the solar photo-Fenton process in the treatment of
contaminated water. Determination of intrinsic kinetic constants for
scale-up”
Miguel Rodríguez,
Solar Energy 79, 360-368 (2005)
“Kinetics of Wet Oxidation Reactions”
V. García-Molina,
J. Bacardit, J. Kallas.
J.Adv.Oxid.Technol 9, 20-26 (2006)
”Biodegradability enhancement
of wastewater containing 4-chlorophenol by means of Photo-Fenton”
J. Bacardit, A. Hultgren,
V. Garcia-Molina,
J.Adv.Oxid.Technol 9, 27-34 (2006)
“Degradation of 2,4-Dichlorophenol by Combining
Photo-Assisted Fenton Reaction and Biological Treatment”
F. Al Momani , C. Sans ,
Water Environmental Research 78, 590-7 (2006)
“Wet
oxidation of 4-chlorophenol Kinetic study”
Veronica
Garcia-Molina, Juha Kallas,
Chemical
Engineering Journal 126,
59–65 (2007)
“Comparative
study of 2,4-dichlorophenol degradation by using
different advanced oxidation processes”
B. Bayarri, O. González, M.
I. Maldonado, J. Giménez and
Journal of Solar Energy Engineering 129, , 61-7 (2007)
"Removal of ortho
and para-cresols by Fenton and Photo-Fenton"
Nissrin Izaoumen, Nadia Ben Abderrazik, Khalid Riffi Temsamani, Santiago
Esplugas
and Enrique Brillas
Afinidad , 63 (526), 449-453 (2006)
"Sulfamethoxazole abatement by photo-Fenton. Toxicity, inhibition and
biodegradability assessment of intermediates."
Oscar González, Carme Sans and Santiago Esplugas
Journal Hazardous Materials 146, 459-464 (2007)
"Simple Models for the control of Photo-Fenton by monitoring H2O2"
Jordi Bacardit, Isabel Oller, Manuel I. Maldonado, Esther Chamarro, Sixto Malato
and Santiago Esplugas
J. Adv. Oxid. Technol. 10, 219-228 (2007)
"Coupled photochemical-biological system to treat biorecalcitrant wastewater"
J. Bacardit, V. García-Molina, B.Bayarri, J.Giménez, E. Chamarro, C. Sans and S.
Esplugas
Water Science & Technology, 55(12), 95-100 (2007)
"Ozonation and advanced oxidation technologies to remove Endocrine Disrupting
Chemicals (EDCs) and Pharmaceuticals and Personal Care Products (PPCPs) in water
effluents"
S. Esplugas, D. M. Bila, L. G. T. Krause, M. Dezotti
Journal of Hazardous Materials 149 (2007) 631–642
" Eliminación de contaminantes en aguas residuales mediante procesos
fotocataliticos de oxidación avanzada"
Oscar González, Maria Navarro, Bernardí Bayarri, Jaime Giménez y Santiago
Esplugas
Afinidad, 64 (528), 171-176 (2007)
"Study of the wavelength effect in the heterogeneous photocatalysis"
B. Bayarri, M. N Abellán, J. Giménez, S. Esplugas
CATALYSIS TODAY 129 (2007) 231-239
"Effect of salinity on photo-Fenton process"
Jordi Bacardit*, Julia Stötzner, Esther Chamarro and Santiago Esplugas
Enviado Ind.Eng.Chem. numero especial A. CASSANO ((Manuscript Number:
ie070154o Author Security Key: AKW45) Enero 2007
Accepted publication may 2007-05-14
Ind. Eng. Chem. Res. 46 (2007) 7615-7619